Gold - Au

General Information

Discovery

Gold was known to ancient civilisations, and has always been a valued metal.

Appearance

Of all the elements, gold is the most beautiful. It is a soft metal with a characteristic yellow colour and sheen.

Source

Gold is found in nature both free in veins and combined in alluvial deposits. About two thirds of the world. s output comes from South Africa. Refining is usually by electrolysis, but gold in ores is recovered by a smelting process.

Uses

Gold is used for coinage and is a standard for monetary systems in many countries. It is also used extensively in jewellery. The term carat expresses the amount of gold present in an alloy; 24 carat is pure gold, and most jewellery is 9 carat gold. Gold is used in dental work, and the isotope
198Au, with a half-life of 2.7 days, is used for treating cancer. A gold compound is used in certain cases to treat arthritis. Another gold compound is used in photography for toning the silver image.

Biological Role

Gold has no known biological role, and is non-toxic.

General Information

Gold has the highest malleability and ductility of any element. It is unaffected by air, water, all acids except aqua regia, and alkalis. It is a good conductor of heat and electricity. It is also a good reflector of infra-red radiation, and as it is inert makes an excellent coating for space satellites.




  Physical Information    
  Atomic Number   79
  Relative Atomic Mass (12C=12.000)   196.97
  Melting Point/K   1337.58
  Boiling Point/K   3080
  Density/kg m-3   19320 (293K)
  Ground State Electron Configuration   [Xe]4f145d106s1
  Electron Affinity(M-M-)/kJ mol-1   223


  Key Isotopes          
  nuclide 195Au 197Au 198Au 199Au  
  atomic mass   196.97      
  natural abundance 0% 100% 0% 0%  
  half-life 183 days stable 2.69 days 3.15 days  


Other Information  
Enthalpy of Fusion/kJ mol-1 12.7
Enthalpy of Vaporisation/kJ mol-1 343.1
     
Oxidation States  
main AuIII
others Au-I, AuO, AuI, AuII, AuV,
  AuVII
     
Covalent Bonds /kJ mol-1  
not applicable    
  Ionisation Energies/kJ mol-1
  M - M+ 890.1
  M+ - M2+ 1980
  M2+ - M3+ 2900
  M3+ - M4+ 4200
  M4+ - M5+ 5600
  M5+ - M6+ 7000
  M6+ - M7+ 9300
  M7+ - M8+ 11000
  M8+ - M9+ 12800
  M9+ - M10+ 14800